TY - JOUR TI - Tunable polyesterification of xylitol: from linear to crosslinked structures PB - John Wiley and Sons Ltd PY - 2017 issn 0959-8103 AB - The copolymerization by condensation chemistry of succinic acid and xylitol, a byproduct from the sugarcane and alcohol industry, is reported. Two methodologies were studied concerning succinic acid, with and without carboxylic acid activation, yielding crosslinked and linear low molecular weight polymers, respectively. All polymerizations were carried out at reaction times in the range from 36 to 80 h, with a molar mass ratio of 1:1 and 1:3. Linear and crosslinked polyesters were analyzed by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry, DSC and TGA, and structural characterization was carried out by Fourier transform infrared spectroscopy and NMR. © 2016 Society of Chemical Industry. © 2016 Society of Chemical Industry KW - Polímeros KW - Acido succínico KW - Xilitol KW - Copolimerización KW - Espectroscopia infrarroja transformadora de Fourie KW - Transformaciones (Matemáticas) KW - Biología KW - Biology KW - Ecología KW - Ecology KW - Conservación de la biodiversidad KW - Biodiversity conservation KW - Métodos de investigación en bioquímica KW - Research biochemistry UR - http://repository.icesi.edu.co/biblioteca_digital/handle/10906/82547 ER -