TY  -  JOUR 
TI  - Acyclic diene metathesis polymerization: History, methods and applications
PB  - Elsevier Ltd
PY  - 2017
issn 0079-6700
AB  - Acyclic Diene Metathesis (ADMET) polymerization was established decades ago and has since developed into a robust and reliable technique. A wide range of different, new materials exhibiting unique properties has been produced via ADMET polymerization since its development. This versatile technique allows, through the right combination of monomer design and choice of catalyst, the synthesis of various functional polymers in addition to a precise control over primary structure. Systematic studies on precise ADMET polymers have greatly contributed to a better understanding of how branch identity and its distribution along the polymer backbone affect the thermal/electronic properties, crystallization, molecular dynamics and morphology of different materials. This article presents an extensive review of how ADMET started, the mechanism that underlies the structural features of ADMET polymers and the different strategies and techniques that have been developed over the years to overcome common synthetic challenges. Monomer synthesis methods are also discussed in detail, providing an important overview of the limitations and advantages of using ADMET as a polymerization technique. Many examples are given of functional ADMET polymers that have been developed by research groups all over the world. © 2016 Elsevier B.V.
KW  - Biología
KW  - Ecología
KW  - Conservación de la biodiversidad
KW  - Métodos de investigación en bioquímica
KW  - Biology
KW  - Ecology
KW  - Biodiversity conservation
KW  - Biochemistry research
UR  - http://hdl.handle.net/10906/81727
ER  -