Effect of the synthetic method on the catalytic activity of alumina: Epoxidation of cyclohexene

Abstract

Al2O3 was prepared from different inorganic precursors via the Pechini method and compared with Al2O3 prepared by the sol–gel method. Structural characterization of these materials was carried out by FTIR, X-ray diffraction (XRD), N2 adsorption at −196°C and transmission electron microscopy (TEM). The solids were tested in the epoxidation of cyclohexene and a difference in their catalytic activities was observed. The characterization results indicate that the samples prepared by Pechini have a mixture of γ-alumina and boehmite, a condition favoring catalytic activity, whereas the sol–gel sample is less crystalline due to higher boehmite content. These results indicate that both the nature of the precursor and the method of synthesis strongly affect the catalytic activity of Al2O3.